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| H | Audax Italiano | - | Colo-Colo | 0:2 (0:2) | ||
| R | Colo-Colo | - | Audax Italiano | 4:5 (2:1) | ||
| H: 20.11.2012 22:00 | R: 25.11.2012 00:00 | Sieger: Colo-Colo | ||||
| H | Huachipato | - | Palestino | 1:1 (0:1) | ||
| R | Palestino | - | Huachipato | 1:2 (0:1) | ||
| H: 21.11.2012 00:30 | R: 24.11.2012 21:45 | Sieger: Huachipato | ||||
| H | Unión Española | - | Universidad de Chile | 0:0 (0:0) | ||
| R | Universidad de Chile | - | Unión Española | 1:4 (1:0) | ||
| H: 21.11.2012 23:00 | R: 25.11.2012 21:45 | Sieger: Unión Española | ||||
| H | Rangers | - | Deportes Iquique | 1:0 (0:0) | ||
| R | Deportes Iquique | - | Rangers | 0:1 (0:0) | ||
| H: 22.11.2012 01:15 | R: 26.11.2012 00:00 | Sieger: Rangers | ||||
