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| H | AC Milan | - | FC Barcelona | 0:1 (0:0) | ||
| R | FC Barcelona | - | AC Milan | 0:0 (0:0) | ||
| H: 18.04.2006 20:45 | R: 26.04.2006 20:45 | Sieger: FC Barcelona | ||||
| H | Arsenal FC | - | Villarreal CF | 1:0 (1:0) | ||
| R | Villarreal CF | - | Arsenal FC | 0:0 (0:0) | ||
| H: 19.04.2006 20:45 | R: 25.04.2006 20:45 | Sieger: Arsenal FC | ||||
