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| H | Newell's Old Boys | - | Vélez Sarsfield | 0:1 (0:0) | ||
| R | Vélez Sarsfield | - | Newell's Old Boys | 1:2 (0:2) | ||
| H: 25.04.2013 02:15 | R: 16.05.2013 00:15 | Sieger: Newell's Old Boys | ||||
| H | Real Garcilaso | - | Nacional | 1:0 (1:0) | ||
| R | Nacional | - | Real Garcilaso | 1:4 (0:0, 1:0, 1:0) i.E. | ||
| H: 26.04.2013 03:15 | R: 10.05.2013 02:15 | Sieger: Real Garcilaso | ||||
| H | Tigre | - | Club Olimpia | 2:1 (1:0) | ||
| R | Club Olimpia | - | Tigre | 2:0 (0:0) | ||
| H: 01.05.2013 01:15 | R: 17.05.2013 01:00 | Sieger: Club Olimpia | ||||
| H | Club Tijuana | - | Palmeiras | 0:0 (0:0) | ||
| R | Palmeiras | - | Club Tijuana | 1:2 (0:1) | ||
| H: 01.05.2013 03:30 | R: 15.05.2013 03:00 | Sieger: Club Tijuana | ||||
| H | Grêmio Porto Alegre | - | Santa Fe | 2:1 (1:0) | ||
| R | Santa Fe | - | Grêmio Porto Alegre | 1:0 (0:0) | ||
| H: 02.05.2013 00:30 | R: 17.05.2013 03:30 | Sieger: Santa Fe | ||||
| H | Boca Juniors | - | Corinthians SP | 1:0 (0:0) | ||
| R | Corinthians SP | - | Boca Juniors | 1:1 (0:1) | ||
| H: 02.05.2013 02:50 | R: 16.05.2013 03:00 | Sieger: Boca Juniors | ||||
| H | São Paulo FC | - | Atlético Mineiro | 1:2 (1:1) | ||
| R | Atlético Mineiro | - | São Paulo FC | 4:1 (1:0) | ||
| H: 03.05.2013 01:15 | R: 09.05.2013 03:00 | Sieger: Atlético Mineiro | ||||
| H | Emelec | - | Fluminense RJ | 2:1 (1:1) | ||
| R | Fluminense RJ | - | Emelec | 2:0 (1:0) | ||
| H: 03.05.2013 03:30 | R: 09.05.2013 03:00 | Sieger: Fluminense RJ | ||||
