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| H | Lanús | - | Universidad de Chile | 4:0 (3:0) | ||
| R | Universidad de Chile | - | Lanús | 1:0 (0:0) | ||
| H: 19.09.2013 01:15 | R: 26.09.2013 00:30 | Sieger: Lanús | ||||
| H | La Equidad | - | Vélez Sarsfield | 1:2 (0:0) | ||
| R | Vélez Sarsfield | - | La Equidad | 2:1 (0:1) | ||
| H: 19.09.2013 03:30 | R: 03.10.2013 02:15 | Sieger: Vélez Sarsfield | ||||
| H | Liga de Loja | - | River Plate | 2:1 (1:0) | ||
| R | River Plate | - | Liga de Loja | 2:0 (1:0) | ||
| H: 20.09.2013 02:15 | R: 27.09.2013 00:30 | Sieger: River Plate | ||||
| H | Coritiba - PR | - | Itagüi Ditaires | 0:1 (0:0) | ||
| R | Itagüi Ditaires | - | Coritiba - PR | 2:1 (0:1) | ||
| H: 25.09.2013 02:00 | R: 25.10.2013 03:00 | Sieger: Itagüi Ditaires | ||||
| H | Ponte Preta | - | Deportivo Pasto | 2:0 (1:0) | ||
| R | Deportivo Pasto | - | Ponte Preta | 1:0 (0:0) | ||
| H: 26.09.2013 00:30 | R: 23.10.2013 02:15 | Sieger: Ponte Preta | ||||
| H | Libertad | - | Sport Recife - PE | 2:0 (2:0) | ||
| R | Sport Recife - PE | - | Libertad | 1:2 (0:1) | ||
| H: 26.09.2013 02:50 | R: 24.10.2013 02:10 | Sieger: Libertad | ||||
| H | São Paulo FC | - | Universidad Católica | 1:1 (1:1) | ||
| R | Universidad Católica | - | São Paulo FC | 3:4 (2:2) | ||
| H: 27.09.2013 03:00 | R: 24.10.2013 01:50 | Sieger: São Paulo FC | ||||
| H | Atlético Nacional | - | Bahia - BA | 1:0 (1:0) | ||
| R | Bahia - BA | - | Atlético Nacional | 3:4 (1:0, 1:0, 1:0) i.E. | ||
| H: 27.09.2013 03:00 | R: 25.10.2013 00:30 | Sieger: Atlético Nacional | ||||
