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| H | Águilas CF | - | Albacete | 3:3 | ||
| R | Albacete | - | Águilas CF | 1:1 i.E. | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: Águilas CF | ||||
| H | RSD Alcalá | - | Sestao SC | 0:0 | ||
| R | Sestao SC | - | RSD Alcalá | 0:1 | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: RSD Alcalá | ||||
| H | CD O Carballiño | - | Elche CF | 0:1 | ||
| R | Elche CF | - | CD O Carballiño | 0:0 | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: Elche CF | ||||
| H | Real Avilés | - | Real Ávila CF | 1:1 | ||
| R | Real Ávila CF | - | Real Avilés | 2:2 i.E. | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: Real Avilés | ||||
| H | Atlético Baleares | - | CD Mirandés | 1:1 | ||
| R | CD Mirandés | - | Atlético Baleares | 1:2 | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: Atlético Baleares | ||||
| H | Barakaldo CF | - | Real Oviedo | 0:4 | ||
| R | Real Oviedo | - | Barakaldo CF | 3:0 | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: Real Oviedo | ||||
| H | CD Basconia | - | CD Tenerife | 0:1 | ||
| R | CD Tenerife | - | CD Basconia | 2:0 | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: CD Tenerife | ||||
| H | CD Binéfar | - | Real Betis | 0:1 | ||
| R | Real Betis | - | CD Binéfar | 4:0 | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: Real Betis | ||||
| H | CD Los Boliches | - | Cádiz CF | 0:1 | ||
| R | Cádiz CF | - | CD Los Boliches | 2:0 | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: Cádiz CF | ||||
| H | RCD Carabanchel | - | CD Badajoz | 3:3 | ||
| R | CD Badajoz | - | RCD Carabanchel | 8:1 | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: CD Badajoz | ||||
| H | Cartagena FC | - | Real Valladolid | 0:2 | ||
| R | Real Valladolid | - | Cartagena FC | 2:2 | ||
| H: 08.11.1990 | R: 20.11.1990 | Sieger: Real Valladolid | ||||
| H | AD Ceuta | - | Real Burgos | 2:1 | ||
| R | Real Burgos | - | AD Ceuta | 3:1 | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: Real Burgos | ||||
| H | SD Compostela | - | CD Málaga | 1:1 | ||
| R | CD Málaga | - | SD Compostela | 3:0 | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: CD Málaga | ||||
| H | Córdoba CF | - | Real Murcia | 2:0 | ||
| R | Real Murcia | - | Córdoba CF | 3:0 | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: Real Murcia | ||||
| H | SCD Durango | - | SD Eibar | 2:2 | ||
| R | SD Eibar | - | SCD Durango | 0:2 | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: SCD Durango | ||||
| H | Deportivo La Coruña | - | CD Estepona (old) | 4:0 | ||
| R | CD Estepona (old) | - | Deportivo La Coruña | 1:0 | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: Deportivo La Coruña | ||||
| H | Andorra CF | - | Orihuela Deportiva CF | 0:2 | ||
| R | Orihuela Deportiva CF | - | Andorra CF | 1:0 | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: Orihuela Deportiva CF | ||||
| H | CF Gandia | - | UD Las Palmas | 3:0 | ||
| R | UD Las Palmas | - | CF Gandia | 8:0 | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: UD Las Palmas | ||||
| H | Getafe CF | - | UE Lleida | 2:0 | ||
| R | UE Lleida | - | Getafe CF | 1:1 | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: Getafe CF | ||||
| H | Gimnástica Torrelavega | - | RCD Mallorca | 1:0 | ||
| R | RCD Mallorca | - | Gimnástica Torrelavega | 6:0 | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: RCD Mallorca | ||||
| H | Club Hispano | - | CD San Roque | 0:1 | ||
| R | CD San Roque | - | Club Hispano | 0:0 | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: CD San Roque | ||||
| H | SD Huesca | - | Xerez CD | 0:0 | ||
| R | Xerez CD | - | SD Huesca | 0:2 | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: SD Huesca | ||||
| H | CD Izarra | - | FC Andorra | 1:3 | ||
| R | FC Andorra | - | CD Izarra | 2:1 | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: FC Andorra | ||||
| H | CD Lalín | - | RC Celta | 1:0 | ||
| R | RC Celta | - | CD Lalín | 2:0 | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: RC Celta | ||||
| H | CD Manacor | - | CD Logroñés | 1:1 | ||
| R | CD Logroñés | - | CD Manacor | 3:0 | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: CD Logroñés | ||||
| H | AEC Manlleu | - | UD Salamanca | 1:1 | ||
| R | UD Salamanca | - | AEC Manlleu | 2:0 | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: UD Salamanca | ||||
| H | Atlético Marbella | - | Athletic Bilbao | 0:0 | ||
| R | Athletic Bilbao | - | Atlético Marbella | 1:0 | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: Athletic Bilbao | ||||
| H | CD Marino | - | Benidorm CD | 1:0 | ||
| R | Benidorm CD | - | CD Marino | 2:0 | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: Benidorm CD | ||||
| H | CD Maspalomas | - | Real Zaragoza | 0:4 | ||
| R | Real Zaragoza | - | CD Maspalomas | 4:0 | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: Real Zaragoza | ||||
| H | CP Mérida | - | CE Sabadell | 1:1 | ||
| R | CE Sabadell | - | CP Mérida | 5:3 | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: CE Sabadell | ||||
| H | CD Numancia | - | CD Castellón | 1:3 | ||
| R | CD Castellón | - | CD Numancia | 1:0 | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: CD Castellón | ||||
| H | UD Orotava | - | Rayo Vallecano | 0:1 | ||
| R | Rayo Vallecano | - | UD Orotava | 5:1 | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: Rayo Vallecano | ||||
| H | SD Ponferradina | - | UE Figueres | 0:0 | ||
| R | UE Figueres | - | SD Ponferradina | 0:1 | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: SD Ponferradina | ||||
| H | Pontevedra CF | - | Sporting Gijón | 3:3 | ||
| R | Sporting Gijón | - | Pontevedra CF | 3:1 | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: Sporting Gijón | ||||
| H | Racing Santander | - | Torrent CF | 0:0 | ||
| R | Torrent CF | - | Racing Santander | 0:3 | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: Racing Santander | ||||
| H | UE Sant Andreu | - | Levante UD | 2:0 | ||
| R | Levante UD | - | UE Sant Andreu | 1:0 | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: UE Sant Andreu | ||||
| H | Club Siero | - | CA Osasuna | 1:8 | ||
| R | CA Osasuna | - | Club Siero | 8:1 | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: CA Osasuna | ||||
| H | Tomelloso CF | - | CF Sporting Mahonés | 1:1 | ||
| R | CF Sporting Mahonés | - | Tomelloso CF | 4:3 i.E. | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: CF Sporting Mahonés | ||||
| H | FC Torrevieja | - | Espanyol Barcelona | 2:3 | ||
| R | Espanyol Barcelona | - | FC Torrevieja | 3:0 | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: Espanyol Barcelona | ||||
| H | CF Valdepeñas | - | Palamós CF | 3:1 | ||
| R | Palamós CF | - | CF Valdepeñas | 3:0 | ||
| H: 08.11.1990 | R: 21.11.1990 | Sieger: Palamós CF | ||||
