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| H | CD Tenerife | - | Real Madrid | 2:1 (2:0) | ||
| R | Real Madrid | - | CD Tenerife | 0:3 (0:1) | ||
| H: 25.01.1994 22:00 | R: 01.02.1994 21:00 | Sieger: CD Tenerife | ||||
| H | Real Oviedo | - | RC Celta | 1:0 (1:0) | ||
| R | RC Celta | - | Real Oviedo | 5:0 (1:0) | ||
| H: 26.01.1994 20:30 | R: 02.02.1994 21:00 | Sieger: RC Celta | ||||
| H | Real Zaragoza | - | Sevilla FC | 2:1 (1:0) | ||
| R | Sevilla FC | - | Real Zaragoza | 1:1 (1:0) | ||
| H: 26.01.1994 20:45 | R: 02.02.1994 21:00 | Sieger: Real Zaragoza | ||||
| H | Real Betis | - | FC Barcelona | 0:0 (0:0) | ||
| R | FC Barcelona | - | Real Betis | 0:1 (0:1) | ||
| H: 26.01.1994 21:00 | R: 03.02.1994 21:00 | Sieger: Real Betis | ||||
