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| H | Alicante CF | - | Deportivo La Coruña | 1:1 (1:0) | ||
| R | Deportivo La Coruña | - | Alicante CF | 4:1 (2:1) | ||
| H: 07.01.2003 21:30 | R: 15.01.2003 20:45 | Sieger: Deportivo La Coruña | ||||
| H | Real Unión | - | CA Osasuna | 0:4 (0:2) | ||
| R | CA Osasuna | - | Real Unión | 1:1 (0:1) | ||
| H: 08.01.2003 20:15 | R: 15.01.2003 20:30 | Sieger: CA Osasuna | ||||
| H | Real Murcia | - | CD Alavés | 0:0 (0:0) | ||
| R | CD Alavés | - | Real Murcia | 1:2 (0:0) | ||
| H: 08.01.2003 21:00 | R: 15.01.2003 20:30 | Sieger: Real Murcia | ||||
| H | RCD Mallorca | - | Real Valladolid | 2:2 (1:1) | ||
| R | Real Valladolid | - | RCD Mallorca | 1:4 (0:3) | ||
| H: 08.01.2003 21:00 | R: 15.01.2003 21:00 | Sieger: RCD Mallorca | ||||
| H | Terrassa FC | - | Real Madrid | 3:3 (0:1) | ||
| R | Real Madrid | - | Terrassa FC | 4:2 (2:0) | ||
| H: 08.01.2003 21:00 | R: 14.01.2003 21:30 | Sieger: Real Madrid | ||||
| H | CD Numancia | - | Sevilla FC | 1:3 (0:1) | ||
| R | Sevilla FC | - | CD Numancia | 2:1 (1:0) | ||
| H: 08.01.2003 21:00 | R: 15.01.2003 21:00 | Sieger: Sevilla FC | ||||
| H | Real Betis | - | Recreativo Huelva | 0:0 (0:0) | ||
| R | Recreativo Huelva | - | Real Betis | 1:0 (0:0) | ||
| H: 08.01.2003 21:00 | R: 15.01.2003 21:00 | Sieger: Recreativo Huelva | ||||
| H | Xerez CD | - | Atlético Madrid | 0:1 (0:1) | ||
| R | Atlético Madrid | - | Xerez CD | 3:0 (1:0) | ||
| H: 08.01.2003 21:00 | R: 15.01.2003 21:00 | Sieger: Atlético Madrid | ||||
