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| H | FC Barcelona | - | Manchester United | -:- | ||
| R | Manchester United | - | FC Barcelona | -:- | ||
| H: 16.02.2023 18:45 | R: 23.02.2023 21:00 | |||||
| H | Shakhtar Donetsk | - | Stade Rennes | -:- | ||
| R | Stade Rennes | - | Shakhtar Donetsk | -:- | ||
| H: 16.02.2023 18:45 | R: 23.02.2023 21:00 | |||||
| H | AFC Ajax | - | 1. FC Union Berlin | -:- |
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| R | 1. FC Union Berlin | - | AFC Ajax | -:- |
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| H: 16.02.2023 18:45 | R: 23.02.2023 21:00 | |||||
| H | RB Salzburg | - | AS Roma | -:- |
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| R | AS Roma | - | RB Salzburg | -:- |
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| H: 16.02.2023 18:45 | R: 23.02.2023 21:00 | |||||
| H | Juventus | - | FC Nantes | -:- | ||
| R | FC Nantes | - | Juventus | -:- | ||
| H: 16.02.2023 21:00 | R: 23.02.2023 18:45 | |||||
| H | Sporting CP | - | FC Midtjylland | -:- | ||
| R | FC Midtjylland | - | Sporting CP | -:- | ||
| H: 16.02.2023 21:00 | R: 23.02.2023 18:45 | |||||
| H | Bayer Leverkusen | - | AS Monaco | -:- |
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| R | AS Monaco | - | Bayer Leverkusen | -:- |
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| H: 16.02.2023 21:00 | R: 23.02.2023 18:45 | |||||
| H | Sevilla FC | - | PSV Eindhoven | -:- | ||
| R | PSV Eindhoven | - | Sevilla FC | -:- | ||
| H: 16.02.2023 21:00 | R: 23.02.2023 18:45 | |||||
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