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| H | Udinese Calcio | - | ACF Fiorentina | 2:1 (1:1) | ||
| R | ACF Fiorentina | - | Udinese Calcio | 2:0 (1:0) | ||
| H: 04.02.2014 21:00 | R: 11.02.2014 21:00 | Sieger: ACF Fiorentina | ||||
| H | AS Roma | - | SSC Napoli | 3:2 (2:0) | ||
| R | SSC Napoli | - | AS Roma | 3:0 (1:0) | ||
| H: 05.02.2014 20:45 | R: 12.02.2014 20:45 | Sieger: SSC Napoli | ||||
