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| 23.08.2011 | 20:30 | Greenock Morton FC | - | St. Mirren FC | 3:4 (2:1) | |
| 20:45 | Hibernian FC | - | Berwick Rangers | 5:0 (2:0) | ||
| 20:45 | East Fife FC | - | Dunfermline Athletic | 2:1 (1:1) | ||
| 20:45 | Airdrie United FC | - | Raith Rovers | 2:0 (2:0) | ||
| 20:45 | Queen Of The South | - | Forfar Athletic | 3:0 (1:0) | ||
| 20:45 | Hamilton Academical | - | Ross County FC | 1:2 (1:0) | ||
| 20:45 | Aberdeen FC | - | Dundee FC | 1:0 (1:0) | ||
| 24.08.2011 | 20:30 | Falkirk FC | - | Stenhousemuir FC | 3:1 (0:1) | |
| 20:30 | Ayr United | - | Inverness CT | 1:0 (0:0) | ||
| 20:45 | St. Johnstone FC | - | Livingston FC | 3:0 (3:0) | ||
| 20:45 | Clyde FC | - | Motherwell FC | 0:4 (0:2) |
