| Ch. League | 04.04.07 | Chelsea FC | - | Valencia CF | 1:1 | ||||
| Ch. League | 10.04.07 | Valencia CF | - | Chelsea FC | 1:2 | ||||
| Ch. League | 03.10.07 | Valencia CF | - | Chelsea FC | 1:2 | ||||
| Ch. League | 11.12.07 | Chelsea FC | - | Valencia CF | 0:0 | ||||
| Ch. League | 28.09.11 | Valencia CF | - | Chelsea FC | 1:1 |  |
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| Ch. League | 05.12.12 | Lille OSC | - | Valencia CF | 0:1 |
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