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| H | Lazio Roma | - | Modena FC | 5:0 (2:0) | ||
| R | Modena FC | - | Lazio Roma | 1:4 (1:1) | ||
| H: 30.08.1994 | R: 21.09.1994 | Sieger: Lazio Roma | ||||
| H | US Fiorenzuola | - | AS Roma | 0:3 (0:1) | ||
| R | AS Roma | - | US Fiorenzuola | 2:1 (1:0) | ||
| H: 31.08.1994 17:45 | R: 22.09.1994 20:30 | Sieger: AS Roma | ||||
| H | AC Milan | - | US Palermo | 0:1 (0:1) | ||
| R | US Palermo | - | AC Milan | 2:3 (0:1, 0:1, 0:1) i.E. | ||
| H: 31.08.1994 20:30 | R: 21.09.1994 | Sieger: AC Milan | ||||
| H | Calcio Padova | - | Inter | 0:3 (0:1) | ||
| R | Inter | - | Calcio Padova | 0:1 (0:1) | ||
| H: 31.08.1994 20:30 | R: 21.09.1994 | Sieger: Inter | ||||
| H | Calcio Como | - | US Foggia | 0:2 (0:1) | ||
| R | US Foggia | - | Calcio Como | 5:0 (2:0) | ||
| H: 31.08.1994 20:30 | R: 21.09.1994 | Sieger: US Foggia | ||||
| H | Cagliari Calcio | - | Atalanta | 1:0 (0:0) | ||
| R | Atalanta | - | Cagliari Calcio | 2:1 (1:1) | ||
| H: 31.08.1994 20:30 | R: 21.09.1994 | Sieger: Cagliari Calcio | ||||
| H | Parma AC | - | AC Perugia | 4:0 (4:0) | ||
| R | AC Perugia | - | Parma AC | 1:0 (1:0) | ||
| H: 31.08.1994 20:30 | R: 21.09.1994 | Sieger: Parma AC | ||||
| H | Udinese Calcio | - | ACF Fiorentina | 2:2 (2:2) | ||
| R | ACF Fiorentina | - | Udinese Calcio | 2:0 (0:0) | ||
| H: 31.08.1994 20:30 | R: 21.09.1994 | Sieger: ACF Fiorentina | ||||
| H | Sampdoria | - | Vicenza Calcio | 5:1 (2:0) | ||
| R | Vicenza Calcio | - | Sampdoria | 2:1 (1:0) | ||
| H: 31.08.1994 20:30 | R: 21.09.1994 | Sieger: Sampdoria | ||||
| H | AS Bari | - | Piacenza Calcio | 0:1 (0:0) | ||
| R | Piacenza Calcio | - | AS Bari | 1:1 (0:0) | ||
| H: 31.08.1994 20:30 | R: 21.09.1994 | Sieger: Piacenza Calcio | ||||
| H | SSC Napoli | - | AS Fidelis Andria | 3:2 (1:0) | ||
| R | AS Fidelis Andria | - | SSC Napoli | 1:1 (1:0) | ||
| H: 31.08.1994 20:30 | R: 21.09.1994 | Sieger: SSC Napoli | ||||
| H | US Cremonese | - | US Lecce | 1:1 (1:0) | ||
| R | US Lecce | - | US Cremonese | 2:2 (0:0, 1:1) n.V. | ||
| H: 31.08.1994 20:30 | R: 21.09.1994 | Sieger: US Cremonese | ||||
| H | AC Cesena | - | Genoa CFC | 0:1 (0:0) | ||
| R | Genoa CFC | - | AC Cesena | 2:0 (1:0) | ||
| H: 31.08.1994 20:30 | R: 21.09.1994 | Sieger: Genoa CFC | ||||
| H | AC Reggiana | - | Brescia Calcio | 1:0 (1:0) | ||
| R | Brescia Calcio | - | AC Reggiana | 0:2 Wert. | ||
| H: 31.08.1994 20:30 | R: 21.09.1994 | Sieger: AC Reggiana | ||||
| H | Juventus | - | Chievo Verona | 0:0 (0:0) | ||
| R | Chievo Verona | - | Juventus | 1:3 (0:2) | ||
| H: 31.08.1994 20:30 | R: 21.09.1994 | Sieger: Juventus | ||||
| H | AC Monza | - | Torino FC | 0:1 (0:0) | ||
| R | Torino FC | - | AC Monza | 4:2 (1:1) | ||
| H: 01.09.1994 20:30 | R: 21.09.1994 | Sieger: Torino FC | ||||
