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| H | Real Madrid | - | Athletic Bilbao | 1:0 | ||
| R | Athletic Bilbao | - | Real Madrid | 2:0 n.V. | ||
| H: 13.03.1985 | R: 03.04.1985 | Sieger: Athletic Bilbao | ||||
| H | Real Sociedad | - | CE Sabadell | 1:0 | ||
| R | CE Sabadell | - | Real Sociedad | 0:0 | ||
| H: 13.03.1985 | R: 03.04.1985 | Sieger: Real Sociedad | ||||
| H | Real Betis | - | RCD Mallorca | 4:0 | ||
| R | RCD Mallorca | - | Real Betis | 2:1 | ||
| H: 13.03.1985 | R: 03.04.1985 | Sieger: Real Betis | ||||
| H | FC Barcelona | - | Hércules CF | 5:0 | ||
| R | Hércules CF | - | FC Barcelona | 1:0 | ||
| H: 13.03.1985 | R: 03.04.1985 | Sieger: FC Barcelona | ||||
| H | Sporting Gijón | - | Valencia CF | 0:0 | ||
| R | Valencia CF | - | Sporting Gijón | 1:4 i.E. | ||
| H: 13.03.1985 | R: 03.04.1985 | Sieger: Sporting Gijón | ||||
| H | Deportivo La Coruña | - | Atlético Madrid | 1:1 | ||
| R | Atlético Madrid | - | Deportivo La Coruña | 5:2 | ||
| H: 13.03.1985 | R: 03.04.1985 | Sieger: Atlético Madrid | ||||
| H | CD Castellón | - | CD Tenerife | 2:0 | ||
| R | CD Tenerife | - | CD Castellón | 2:2 | ||
| H: 13.03.1985 | R: 03.04.1985 | Sieger: CD Castellón | ||||
| H | Real Zaragoza | - | Cádiz CF | 1:2 | ||
| R | Cádiz CF | - | Real Zaragoza | 3:5 i.E. | ||
| H: 13.03.1985 | R: 03.04.1985 | Sieger: Real Zaragoza | ||||
