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| H | Real Murcia | - | Real Avilés | 2:2 | ||
| R | Real Avilés | - | Real Murcia | 0:2 | ||
| H: 20.11.1991 | R: 04.12.1991 | Sieger: Real Murcia | ||||
| H | Palamós CF | - | Athletic Bilbao | 0:3 | ||
| R | Athletic Bilbao | - | Palamós CF | 3:0 | ||
| H: 20.11.1991 | R: 04.12.1991 | Sieger: Athletic Bilbao | ||||
| H | CD Tenerife | - | Valencia CF | 1:0 | ||
| R | Valencia CF | - | CD Tenerife | 2:0 | ||
| H: 20.11.1991 | R: 04.12.1991 | Sieger: Valencia CF | ||||
| H | Benidorm CD | - | CP Mérida | 2:1 | ||
| R | CP Mérida | - | Benidorm CD | 0:0 | ||
| H: 20.11.1991 | R: 04.12.1991 | Sieger: Benidorm CD | ||||
| H | Real Sociedad | - | CD Logroñés | 2:1 | ||
| R | CD Logroñés | - | Real Sociedad | 3:1 | ||
| H: 20.11.1991 | R: 04.12.1991 | Sieger: CD Logroñés | ||||
| H | Sevilla FC | - | Espanyol Barcelona | 4:1 | ||
| R | Espanyol Barcelona | - | Sevilla FC | 1:0 | ||
| H: 20.11.1991 | R: 04.12.1991 | Sieger: Sevilla FC | ||||
| H | CD Málaga | - | CD Castellón | 0:1 | ||
| R | CD Castellón | - | CD Málaga | 0:0 | ||
| H: 20.11.1991 | R: 04.12.1991 | Sieger: CD Castellón | ||||
| H | Getafe CF | - | Real Betis | 1:0 | ||
| R | Real Betis | - | Getafe CF | 2:0 | ||
| H: 20.11.1991 | R: 04.12.1991 | Sieger: Real Betis | ||||
| H | Real Zaragoza | - | Deportivo La Coruña | 0:2 | ||
| R | Deportivo La Coruña | - | Real Zaragoza | 3:2 | ||
| H: 20.11.1991 | R: 04.12.1991 | Sieger: Deportivo La Coruña | ||||
| H | SD Compostela | - | Real Burgos | 1:0 | ||
| R | Real Burgos | - | SD Compostela | 2:0 | ||
| H: 20.11.1991 | R: 04.12.1991 | Sieger: Real Burgos | ||||
