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| H | Sporting Gijón | - | FC Barcelona | 0:3 (0:3) | ||
| R | FC Barcelona | - | Sporting Gijón | 1:1 (1:1) | ||
| H: 04.01.1994 20:30 | R: 12.01.1994 20:45 | Sieger: FC Barcelona | ||||
| H | Real Madrid | - | Atlético Madrid | 2:2 (1:1) | ||
| R | Atlético Madrid | - | Real Madrid | 2:3 (1:1) | ||
| H: 04.01.1994 21:00 | R: 13.01.1994 21:30 | Sieger: Real Madrid | ||||
| H | Deportivo La Coruña | - | Real Oviedo | 1:3 (0:3) | ||
| R | Real Oviedo | - | Deportivo La Coruña | 0:1 (0:1) | ||
| H: 05.01.1994 20:30 | R: 12.01.1994 20:15 | Sieger: Real Oviedo | ||||
| H | Espanyol Barcelona | - | Sevilla FC | 0:1 (0:0) | ||
| R | Sevilla FC | - | Espanyol Barcelona | 2:2 (1:1) | ||
| H: 05.01.1994 20:45 | R: 12.01.1994 21:00 | Sieger: Sevilla FC | ||||
| H | CD Logroñés | - | RC Celta | 1:0 (1:0) | ||
| R | RC Celta | - | CD Logroñés | 4:3 (1:0, 1:0, 1:0) i.E. | ||
| H: 05.01.1994 21:00 | R: 12.01.1994 21:00 | Sieger: RC Celta | ||||
| H | CD Tenerife | - | Valencia CF | 3:1 (2:0) | ||
| R | Valencia CF | - | CD Tenerife | 3:2 (2:0) | ||
| H: 05.01.1994 22:00 | R: 12.01.1994 21:00 | Sieger: CD Tenerife | ||||
| H | Real Betis | - | CP Mérida | 3:1 (1:0) | ||
| R | CP Mérida | - | Real Betis | 1:1 (0:0) | ||
| H: 06.01.1994 17:00 | R: 12.01.1994 21:00 | Sieger: Real Betis | ||||
| H | CD Badajoz | - | Real Zaragoza | 1:0 (1:0) | ||
| R | Real Zaragoza | - | CD Badajoz | 3:0 (2:0) | ||
| H: 06.01.1994 17:00 | R: 12.01.1994 20:45 | Sieger: Real Zaragoza | ||||
