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| 13.02.1966 | UE Lleida | - | RC Celta | 1:0 | ||
| Sporting Gijón | - | Racing Santander | 3:3 | |||
| Deportivo La Coruña | - | CE L'Hospitalet | 3:0 | |||
| UP Langreo | - | Real Oviedo | 0:1 | |||
| CE Europa | - | SD Indautxu | 0:1 | |||
| CF Badalona | - | CA Osasuna | 1:0 | |||
| CD Condal | - | Barakaldo CF | 3:1 | |||
| Real Sociedad | - | Burgos CF | 2:0 | |||
| CD Badajoz | - | Real Valladolid | 0:2 | |||
| Cádiz CF | - | CD Mestalla | 1:1 | |||
| Hércules CF | - | UD Melilla | 1:0 | |||
| Real Murcia | - | Algeciras CF | 1:1 | |||
| Rayo Vallecano | - | CD Constància | 3:1 | |||
| Levante UD | - | Recreativo Huelva | 3:1 | |||
| CD Tenerife | - | CF Calvo Sotelo | 1:1 | |||
| CA Ceuta | - | Granada CF | 2:1 |
| 1 | |||||||||
| # | Mannschaft | Sp. | S. | U. | N. | Tore | Dif. | Pk. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Deportivo La Coruña | 23 | 14 | 5 | 4 | 40:15 | 25 | 33:13 |
| 2 |
|
RC Celta | 23 | 13 | 3 | 7 | 45:24 | 21 | 29:17 |
| 3 |
|
Sporting Gijón | 23 | 11 | 6 | 6 | 53:35 | 18 | 28:18 |
| 4 |
|
Real Oviedo | 23 | 11 | 6 | 6 | 31:17 | 14 | 28:18 |
| 5 |
|
CD Condal | 23 | 12 | 2 | 9 | 48:37 | 11 | 26:20 |
| 6 |
|
CF Badalona | 23 | 11 | 3 | 9 | 26:32 | -6 | 25:21 |
| 7 |
|
Real Sociedad | 23 | 11 | 3 | 9 | 42:38 | 4 | 25:21 |
| 8 |
|
UE Lleida | 23 | 8 | 7 | 8 | 33:28 | 5 | 23:23 |
| 9 |
|
CA Osasuna | 23 | 10 | 3 | 10 | 29:32 | -3 | 23:23 |
| 10 |
|
Burgos CF | 23 | 9 | 4 | 10 | 32:36 | -4 | 22:24 |
| 11 |
|
SD Indautxu | 23 | 10 | 2 | 11 | 35:41 | -6 | 22:24 |
| 12 |
|
Racing Santander | 23 | 7 | 7 | 9 | 29:34 | -5 | 21:25 |
| 13 |
|
UP Langreo | 23 | 10 | 1 | 12 | 34:46 | -12 | 21:25 |
| 14 |
|
CE Europa | 23 | 7 | 4 | 12 | 25:36 | -11 | 18:28 |
| 15 |
|
CE L'Hospitalet | 23 | 7 | 0 | 16 | 27:49 | -22 | 14:32 |
| 16 |
|
Barakaldo CF | 23 | 4 | 2 | 17 | 17:46 | -29 | 10:36 |
| 2 | |||||||||
| # | Mannschaft | Sp. | S. | U. | N. | Tore | Dif. | Pk. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Hércules CF | 23 | 13 | 4 | 6 | 32:17 | 15 | 30:16 |
| 2 |
|
CD Mestalla | 23 | 9 | 11 | 3 | 37:30 | 7 | 29:17 |
| 3 |
|
Real Valladolid | 23 | 10 | 8 | 5 | 36:21 | 15 | 28:18 |
| 4 |
|
CD Tenerife | 23 | 11 | 6 | 6 | 35:18 | 17 | 28:18 |
| 5 |
|
Granada CF | 23 | 11 | 5 | 7 | 28:24 | 4 | 27:19 |
| 6 |
|
Algeciras CF | 23 | 11 | 4 | 8 | 24:20 | 4 | 26:20 |
| 7 |
|
CF Calvo Sotelo | 23 | 11 | 4 | 8 | 27:28 | -1 | 26:20 |
| 8 |
|
Rayo Vallecano | 23 | 10 | 5 | 8 | 27:18 | 9 | 25:21 |
| 9 |
|
Levante UD | 23 | 8 | 7 | 8 | 32:20 | 12 | 23:23 |
| 10 |
|
CD Constància | 23 | 8 | 5 | 10 | 26:35 | -9 | 21:25 |
| 11 |
|
Real Murcia | 23 | 8 | 5 | 10 | 21:24 | -3 | 21:25 |
| 12 |
|
Recreativo Huelva | 23 | 7 | 6 | 10 | 19:24 | -5 | 20:26 |
| 13 |
|
Cádiz CF | 23 | 6 | 6 | 11 | 18:25 | -7 | 18:28 |
| 14 |
|
CA Ceuta | 23 | 8 | 2 | 13 | 26:37 | -11 | 18:28 |
| 15 |
|
CD Badajoz | 23 | 3 | 8 | 12 | 17:40 | -23 | 14:32 |
| 16 |
|
UD Melilla | 23 | 5 | 4 | 14 | 17:41 | -24 | 14:32 |
