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| 27.03.1966 | Racing Santander | - | Barakaldo CF | 1:0 | ||
| UE Lleida | - | UP Langreo | 2:0 | |||
| Sporting Gijón | - | CF Badalona | 2:1 | |||
| Burgos CF | - | CE L'Hospitalet | 4:2 | |||
| SD Indautxu | - | Real Oviedo | 2:1 | |||
| CE Europa | - | RC Celta | 2:0 | |||
| CD Condal | - | Deportivo La Coruña | 2:2 | |||
| Real Sociedad | - | CA Osasuna | 2:0 | |||
| Real Valladolid | - | Algeciras CF | 2:2 | |||
| CD Badajoz | - | Levante UD | 0:1 | |||
| Cádiz CF | - | Recreativo Huelva | 1:0 | |||
| Hércules CF | - | CF Calvo Sotelo | 2:0 | |||
| Real Murcia | - | CA Ceuta | 4:1 | |||
| CD Tenerife | - | Rayo Vallecano | 1:0 | |||
| CD Mestalla | - | Granada CF | 0:3 | |||
| UD Melilla | - | CD Constància | 3:1 |
| 1 | |||||||||
| # | Mannschaft | Sp. | S. | U. | N. | Tore | Dif. | Pk. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Deportivo La Coruña | 29 | 17 | 7 | 5 | 48:18 | 30 | 41:17 |
| 2 |
|
RC Celta | 29 | 16 | 5 | 8 | 52:28 | 24 | 37:21 |
| 3 |
|
Sporting Gijón | 29 | 15 | 6 | 8 | 66:45 | 21 | 36:22 |
| 4 |
|
Real Oviedo | 29 | 13 | 8 | 8 | 37:20 | 17 | 34:24 |
| 5 |
|
Burgos CF | 29 | 13 | 5 | 11 | 41:40 | 1 | 31:27 |
| 6 |
|
SD Indautxu | 29 | 14 | 3 | 12 | 47:47 | 0 | 31:27 |
| 7 |
|
Real Sociedad | 29 | 13 | 5 | 11 | 50:46 | 4 | 31:27 |
| 8 |
|
CD Condal | 29 | 13 | 4 | 12 | 54:46 | 8 | 30:28 |
| 9 |
|
CA Osasuna | 29 | 13 | 4 | 12 | 38:40 | -2 | 30:28 |
| 10 |
|
UE Lleida | 29 | 10 | 9 | 10 | 37:31 | 6 | 29:29 |
| 11 |
|
Racing Santander | 29 | 10 | 9 | 10 | 36:39 | -3 | 29:29 |
| 12 |
|
CF Badalona | 29 | 12 | 4 | 13 | 29:39 | -10 | 28:30 |
| 13 |
|
UP Langreo | 29 | 10 | 3 | 16 | 37:57 | -20 | 23:35 |
| 14 |
|
CE Europa | 29 | 9 | 5 | 15 | 31:46 | -15 | 23:35 |
| 15 |
|
CE L'Hospitalet | 29 | 9 | 0 | 20 | 37:63 | -26 | 18:40 |
| 16 |
|
Barakaldo CF | 29 | 5 | 3 | 21 | 24:59 | -35 | 13:45 |
| 2 | |||||||||
| # | Mannschaft | Sp. | S. | U. | N. | Tore | Dif. | Pk. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Hércules CF | 29 | 16 | 7 | 6 | 44:23 | 21 | 39:19 |
| 2 |
|
Granada CF | 29 | 15 | 5 | 9 | 39:29 | 10 | 35:23 |
| 3 |
|
Real Valladolid | 29 | 13 | 9 | 7 | 48:30 | 18 | 35:23 |
| 4 |
|
CD Mestalla | 29 | 10 | 13 | 6 | 44:39 | 5 | 33:25 |
| 5 |
|
Algeciras CF | 29 | 13 | 7 | 9 | 38:29 | 9 | 33:25 |
| 6 |
|
Levante UD | 29 | 12 | 8 | 9 | 41:22 | 19 | 32:26 |
| 7 |
|
CD Tenerife | 29 | 13 | 6 | 10 | 40:30 | 10 | 32:26 |
| 8 |
|
CF Calvo Sotelo | 29 | 12 | 6 | 11 | 32:36 | -4 | 30:28 |
| 9 |
|
Rayo Vallecano | 29 | 11 | 7 | 11 | 33:25 | 8 | 29:29 |
| 10 |
|
Real Murcia | 29 | 12 | 5 | 12 | 30:33 | -3 | 29:29 |
| 11 |
|
Cádiz CF | 29 | 10 | 7 | 12 | 25:27 | -2 | 27:31 |
| 12 |
|
Recreativo Huelva | 29 | 10 | 7 | 12 | 26:29 | -3 | 27:31 |
| 13 |
|
CD Constància | 29 | 9 | 6 | 14 | 32:48 | -16 | 24:34 |
| 14 |
|
CA Ceuta | 29 | 10 | 3 | 16 | 32:46 | -14 | 23:35 |
| 15 |
|
UD Melilla | 29 | 7 | 6 | 16 | 26:50 | -24 | 20:38 |
| 16 |
|
CD Badajoz | 29 | 4 | 8 | 17 | 21:55 | -34 | 16:42 |
