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| H | Deportivo Guadalajara | - | Vélez Sarsfield | 0:0 (0:0) | ||
| R | Vélez Sarsfield | - | Deportivo Guadalajara | 1:2 (0:1) | ||
| H: 10.05.2006 03:15 | R: 21.07.2006 02:45 | Sieger: Deportivo Guadalajara | ||||
| H | LDU Quito | - | Internacional | 2:1 (0:1) | ||
| R | Internacional | - | LDU Quito | 2:0 (0:0) | ||
| H: 11.05.2006 00:30 | R: 20.07.2006 00:15 | Sieger: Internacional | ||||
| H | Estudiantes | - | São Paulo FC | 1:0 (0:0) | ||
| R | São Paulo FC | - | Estudiantes | 4:3 (1:0, 1:0, 1:0) i.E. | ||
| H: 11.05.2006 02:45 | R: 20.07.2006 02:45 | Sieger: São Paulo FC | ||||
| H | River Plate | - | Libertad | 2:2 (0:1) | ||
| R | Libertad | - | River Plate | 3:1 (2:0) | ||
| H: 12.05.2006 02:15 | R: 19.07.2006 02:15 | Sieger: Libertad | ||||
